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great questions and answers
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Web designer Jack Osborne explains his use of semantic elements, with some easy to follow nested element diagrams
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A great slideshow, made in HTML5, with plenty of working examples (browser support permitting). Brings the other reading of HTML5 stuff to life. Will be referring to this a lot.
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an overview of the new features of HTML5
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an intro to some of the new features in HTML5 that don't make it across all browsers, yet are worth using in those that do support them
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Mark Pilgrim's online book in progress is a must-read. He is one of the rare writers who can make this sort of stuff a good read.
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the html5 outline is nicely explained in this article
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some examples of HTML5 in the wild.